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872-36-6

  • Product Name:Vinylene carbonate
  • Molecular Formula:C3H2O3
  • Purity:99%
  • Molecular Weight:86.0471
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Product Details

  • CasNo: 872-36-6
  • Molecular Formula: C3H2O3
  • Appearance: clear colorless to light yellow liquid
  • Cost-effective and customizable Vinylene carbonate 872-36-6 factory

    • Molecular Formula:C3H2O3
    • Molecular Weight:86.0471
    • Appearance/Colour:clear colorless to light yellow liquid 
    • Vapor Pressure:89.9mmHg at 25°C 
    • Melting Point:19-22 °C(lit.) 
    • Refractive Index:n20/D 1.421(lit.)  
    • Boiling Point:79.2 °C at 760 mmHg 
    • Flash Point:53.1 °C 
    • PSA:43.35000 
    • Density:1.42 g/cm3 
    • LogP:0.23280 

    Vinylene carbonate(Cas 872-36-6) Usage

    Application

    Vinylene carbonate (VC) can be used as an electrolytic additive for ionic liquid electrolyte for the formation of lithium-ion batteries. It can also be used in the formation of hybrid solid electrolyte interphase (SEI) for the fabrication of lithium-based batteries.

    Preparation

    Vinylene carbonate is produced by the known method by eliminating hydrogen chloride from chloroethylene glycol carbonate by means of tertiary amines, in particular triethylamine. Chloroethylene glycol carbonate is obtained by free radical chlorination of ethylene glycol carbonate by means of chlorine or sulphuryl chloride. This synthesis was published for the first time in 1953 by Newman and Addor (JACS, 1953, page 1263; JACS 1955, page 3789).

    General Description

    This product has been enhanced for energy efficiency. Carbonate building block offered as a solution in ethyl acetate for more convenient handling. Vinylene carbonate may also be used as a dienophile in Diels-Alder reactions.

    Flammability and Explosibility

    Nonflammable

    Purification Methods

    Purify it by zone melting, or distillation, and stabilize it with 0.5% of 2,6-di-tert-butyl-p-cresol. [Beilstein 19 III/IV 1597, 19/4 V 72.]

    InChI:InChI=1/C3H2O3/c4-3-5-1-2-6-3/h1-2H

    872-36-6 Relevant articles

    -

    Johnson,Patton

    , p. 1042 (1960)

    -

    -

    Dorris et al.

    , p. 1352 (1966)

    -

    Method for producing a vinylene carbonate

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    Paragraph 0032; 0035-0037, (2021/11/02)

    [Problem] to a dehydrochlorination react...

    Preparation method of vinylene carbonate

    -

    Paragraph 0034-0035, (2020/07/21)

    The invention discloses a preparation me...

    Synthesis method of vinylene carbonate

    -

    Paragraph 0017; 0019-0022, (2019/12/02)

    The invention discloses a synthesis meth...

    POLYVINYL ALCOHOL PARTICLES, PHARMACEUTICAL BINDER USING SAME, PHARMACEUTICAL TABLET, SUSTAINED-RELEASE PHARMACEUTICAL TABLET, AND METHOD FOR PRODUCING POLYVINYL ALCOHOL PARTICLES

    -

    , (2017/08/22)

    Provided herein is a polyvinyl alcohol f...

    872-36-6 Process route

    4-chloro-1,3-dioxolan-2-one
    3967-54-2

    4-chloro-1,3-dioxolan-2-one

    vinylene carbonate
    872-36-6

    vinylene carbonate

    triethylamine hydrochloride
    554-68-7

    triethylamine hydrochloride

    Conditions
    Conditions Yield
    With triethylamine; In diethyl ether; for 20h; Heating / reflux;
    With triethylamine; In Dibutyl carbonate; at 50 ℃; for 20h;
    4-chloro-1,3-dioxolan-2-one
    3967-54-2

    4-chloro-1,3-dioxolan-2-one

    vinylene carbonate
    872-36-6

    vinylene carbonate

    2-chloroethanal
    107-20-0

    2-chloroethanal

    acetic acid
    64-19-7,77671-22-8

    acetic acid

    Conditions
    Conditions Yield
    catalyst from examples 1 and 2 (ZnCl2 on silica, calcined); at 200 - 400 ℃; for 6.5 - 332h; Product distribution / selectivity;
    69%

    872-36-6 Upstream products

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      3967-54-2

      4-chloro-1,3-dioxolan-2-one

    • 60-29-7
      60-29-7

      diethyl ether

    • 121-44-8
      121-44-8

      triethylamine

    • 96-49-1
      96-49-1

      [1,3]-dioxolan-2-one

    872-36-6 Downstream products

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      (3aRS,7aSR)-5,6-dimethyl-3a,4,7,7a-tetrahydrobenzo[d][1,3]dioxol-2-one

    Antioxidant BHT 264

    CAS:128-37-0

    Purity:99%

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