Antioxidant BHT 264
CAS:128-37-0
Purity:99%
Contact Now
We will contact you as soon as possible
Your Location：Home >Products >OLED Intermediates >3842-55-5
Product Details
|
Synthesis Reference(s) |
The Journal of Organic Chemistry, 34, p. 4125, 1969 DOI: 10.1021/jo01264a079Synthesis, p. 841, 1980 DOI: 10.1055/s-1980-29230 |
InChI:InChI=1/C15H10ClN3/c16-15-18-13(11-7-3-1-4-8-11)17-14(19-15)12-9-5-2-6-10-12/h1-10H
The present invention relates to an arom...
We report the synthesis, gelation abilit...
The present invention relates to a novel...
Duchenne muscular dystrophy is a fatal d...
1,3,5-trichloro-2,4,6-triazine
phenylboronic acid
2-chloro-4,6-diphenyl-1,3,5-triazine
| Conditions | Yield |
|---|---|
|
With
bis(tricyclohexylphosphine)nickel(II) dichloride; potassium carbonate;
In
tetrahydrofuran;
at 70 ℃;
for 12h;
Reagent/catalyst;
Solvent;
Temperature;
Green chemistry;
|
94.1% |
|
With
sodium carbonate;
tetrakis(triphenylphosphine) palladium(0);
In
water; toluene;
for 8h;
Inert atmosphere;
Reflux;
|
71% |
|
With
tetrakis(triphenylphosphine) palladium(0); sodium carbonate;
In
water; toluene;
for 8h;
Inert atmosphere;
Reflux;
|
71% |
|
With
tetrakis(triphenylphosphine) palladium(0); potassium carbonate;
In
ethanol; water; toluene;
at 120 ℃;
for 12h;
Inert atmosphere;
|
61.2% |
|
With
tetrakis(triphenylphosphine) palladium(0); potassium carbonate;
In
1,4-dioxane; water; toluene;
at 100 ℃;
for 6h;
|
60% |
|
With
tetrakis(triphenylphosphine) palladium(0); potassium carbonate;
In
1,4-dioxane; water; toluene;
at 100 ℃;
for 6h;
|
60% |
|
With
tetrakis(triphenylphosphine) palladium(0); sodium carbonate;
In
ethanol; toluene;
for 4h;
Reflux;
|
48% |
|
With
tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate;
In
5,5-dimethyl-1,3-cyclohexadiene;
for 12h;
Reflux;
|
48% |
|
With
tetrakis(triphenylphosphine) palladium(0); potassium carbonate;
In
water; toluene;
at 100 ℃;
for 12h;
|
46% |
|
With
potassium phosphate; palladium diacetate;
In
tetrahydrofuran;
at 45 ℃;
for 24h;
|
|
|
With
tetrakis(triphenylphosphine) palladium(0); sodium hydroxide;
In
tetrahydrofuran; water;
|
|
|
With
tetra-n-propylammonium bromide; potassium carbonate;
In
toluene;
for 10h;
Inert atmosphere;
Reflux;
|
0.78 g |
bromobenzene
1,3,5-trichloro-2,4,6-triazine
2-chloro-4,6-diphenyl-1,3,5-triazine
| Conditions | Yield |
|---|---|
|
bromobenzene;
With
iodine; magnesium;
In
tetrahydrofuran;
for 4h;
Inert atmosphere;
Reflux;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran;
for 5h;
Inert atmosphere;
|
73.5% |
|
bromobenzene;
With
iodine; magnesium;
In
tetrahydrofuran;
for 1h;
Inert atmosphere;
Reflux;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran;
for 7h;
Reflux;
Inert atmosphere;
|
73.5% |
|
bromobenzene;
With
magnesium;
In
tetrahydrofuran;
at 40 - 50 ℃;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran;
at -5 - 5 ℃;
|
72.8% |
|
bromobenzene;
With
iodine; magnesium;
In
tetrahydrofuran;
at 20 ℃;
for 2h;
Inert atmosphere;
Reflux;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran;
at 0 ℃;
|
68.9% |
|
bromobenzene;
With
iodine; magnesium;
In
tetrahydrofuran;
at 60 ℃;
Inert atmosphere;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran;
at 0 ℃;
Inert atmosphere;
|
65% |
|
bromobenzene;
With
iodine; magnesium;
In
tetrahydrofuran;
at 0 - 65 ℃;
for 2h;
Inert atmosphere;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran;
at 0 - 20 ℃;
for 12h;
Inert atmosphere;
|
64.5% |
|
bromobenzene;
With
iodine; magnesium;
In
tetrahydrofuran;
at 0 - 65 ℃;
for 2h;
Inert atmosphere;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran;
at 0 - 20 ℃;
for 12h;
Inert atmosphere;
|
64.5% |
|
bromobenzene;
With
iodine; magnesium;
In
tetrahydrofuran;
at 0 - 65 ℃;
for 2h;
Inert atmosphere;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran;
at 0 - 20 ℃;
for 12h;
Inert atmosphere;
|
64.5% |
|
bromobenzene;
With
iodine; magnesium;
In
tetrahydrofuran;
at 65 ℃;
for 2.5h;
Inert atmosphere;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran;
at 20 ℃;
for 12h;
Temperature;
Inert atmosphere;
|
64.5% |
|
bromobenzene;
With
iodine; magnesium;
In
tetrahydrofuran;
at 0 - 65 ℃;
for 2.5h;
Inert atmosphere;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran;
at 0 - 20 ℃;
for 12h;
Inert atmosphere;
|
64.5% |
|
bromobenzene;
With
iodine; magnesium;
In
tetrahydrofuran;
at 20 ℃;
Reflux;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran;
at 0 - 50 ℃;
|
62% |
|
bromobenzene;
With
iodine; magnesium;
In
tetrahydrofuran;
for 2h;
Inert atmosphere;
Reflux;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran;
at 0 - 50 ℃;
for 10h;
Inert atmosphere;
|
61% |
|
bromobenzene;
With
nitrogen; iodine; magnesium;
In
tetrahydrofuran;
for 2h;
Reflux;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran;
at 0 - 50 ℃;
for 10h;
|
61% |
|
bromobenzene;
With
iodine; magnesium;
In
tetrahydrofuran;
for 2h;
Inert atmosphere;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran;
at 0 - 50 ℃;
for 10h;
Inert atmosphere;
|
61% |
|
bromobenzene;
With
magnesium;
In
tetrahydrofuran; ethylene dibromide;
at 40 ℃;
for 1.25h;
Inert atmosphere;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran; ethylene dibromide;
at 20 - 35 ℃;
for 24.25h;
Inert atmosphere;
|
54% |
|
bromobenzene;
With
iodine; magnesium;
In
tetrahydrofuran;
Inert atmosphere;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran;
at 35 ℃;
for 12h;
Inert atmosphere;
|
50% |
|
With
iodine; magnesium;
In
benzene;
|
45% |
|
bromobenzene;
With
iodine; magnesium;
In
diethyl ether;
for 2h;
Reflux;
1,3,5-trichloro-2,4,6-triazine;
In
diethyl ether;
for 5h;
Reflux;
|
45% |
|
bromobenzene;
With
iodine; magnesium;
In
diethyl ether;
for 2h;
Reflux;
1,3,5-trichloro-2,4,6-triazine;
In
diethyl ether;
at 10 ℃;
for 5h;
Reflux;
|
45% |
|
bromobenzene;
With
iodine; magnesium;
In
tetrahydrofuran;
for 2h;
Reflux;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran;
at 10 ℃;
for 5h;
Reflux;
|
45% |
|
bromobenzene;
With
iodine; magnesium;
In
diethyl ether;
for 2h;
Reflux;
1,3,5-trichloro-2,4,6-triazine;
In
diethyl ether;
for 5h;
Reflux;
|
45% |
|
bromobenzene;
With
iodine; magnesium;
In
tetrahydrofuran;
for 2h;
Reflux;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran;
at 10 ℃;
for 5h;
|
45% |
|
bromobenzene;
With
iodine; magnesium;
In
diethyl ether;
for 2h;
Reflux;
1,3,5-trichloro-2,4,6-triazine;
In
diethyl ether;
for 5h;
Reflux;
|
45% |
|
bromobenzene;
With
iodine; magnesium;
In
tetrahydrofuran;
for 2h;
Reflux;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran;
at 10 ℃;
for 5h;
Reflux;
|
45% |
|
bromobenzene;
With
magnesium;
In
tetrahydrofuran;
at 70 ℃;
for 1.5h;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran;
at 35 ℃;
|
22.3% |
|
With
magnesium; phenylmagnesium bromide;
In
benzene;
|
|
|
With
n-butyllithium;
In
tetrahydrofuran;
at -78 ℃;
for 8h;
Inert atmosphere;
|
|
|
bromobenzene;
With
magnesium;
In
tetrahydrofuran; ethylene dibromide;
at 20 ℃;
for 3h;
Reflux;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran; ethylene dibromide;
at 35 ℃;
for 18h;
Reflux;
|
1.128 g |
|
bromobenzene;
With
iodine; magnesium;
In
tetrahydrofuran;
for 2h;
Inert atmosphere;
Reflux;
1,3,5-trichloro-2,4,6-triazine;
In
tetrahydrofuran;
at 20 ℃;
for 3h;
Inert atmosphere;
|
1.34 g |
1,3,5-trichloro-2,4,6-triazine
5-nitroso-2,4-diphenyl-imidazole
4,6-diphenyl-1H-[1,3,5]triazin-2-one
N-phenyl benzoyl amide
2,4,6-triphenyl-1,3,5-triazine
(4,6-Diphenyl-1,3,5-triazin-2-yl)phenylamine
4,6-diphenyl-1H-[1,3,5]triazin-2-one
4,6-diphenyl-1H-[1,3,5]triazine-2-thione
